Systematic investigation of thorium(IV)- and uranium(IV)-ligand bonding in dithiophosphonate, thioselenophosphinate, and diselenophosphonate complexes.

Abstract

Homoleptic soft-donor actinide complexes of the general form An[E2PROR']4 were synthesized from salt metathesis between ThCl4(DME)2 or UI4(1,4-dioxane)2 and M[E2PROR'], M = Na, K, to yield 2 (An = Th, E = S, R = 4-MeOC6H4, R' = Me), 3 (An = Th, E = S, R = 4-MeOC6H4, R' = (t)Bu), 4 (An = U, E = S, R = 4-MeOC6H4, R' = Me), 5 (An = Th, E = Se, R = C6H5, R… (More)
DOI: 10.1021/ic401642a

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Cite this paper

@article{Behrle2013SystematicIO, title={Systematic investigation of thorium(IV)- and uranium(IV)-ligand bonding in dithiophosphonate, thioselenophosphinate, and diselenophosphonate complexes.}, author={Andrew C Behrle and Charles Leslie Barnes and Nikolas Kaltsoyannis and Justin R Walensky}, journal={Inorganic chemistry}, year={2013}, volume={52 18}, pages={10623-31} }