Systematic evaluation of molecular recognition phenomena. 3. Selective diphosphate binding to isomeric hexaazamacrocyclic ligands containing xylylic spacers.

Abstract

The crystal structure of 3,7,11,18,22,26-hexaazatricyclo[26.2.2.2(13,16)]tetratriaconta-1(31),13(34),14,16(33),28(32),29-hexaene hexahydrobromide salt [(H6P3)Br6] has been determined by means of X-ray diffraction analysis. It crystallizes with an additional molecule of ethanol and half a molecule of water per molecule of the hydrobromide P3 ligand. The… (More)

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