Synthetic investigation toward apigenin 5-O-glycoside camellianin B as well as the chemical structure revision.

@article{Hu2016SyntheticIT,
  title={Synthetic investigation toward apigenin 5-O-glycoside camellianin B as well as the chemical structure revision.},
  author={Yang Hu and Yuan-Hong Tu and De-Yong Liu and Jinxi Liao and Jian-Song Sun},
  journal={Organic \& biomolecular chemistry},
  year={2016},
  volume={14 21},
  pages={
          4842-7
        }
}
Capitalizing on the Au(i)-catalyzed ortho-alkynylbenzoate glycosylation method, the first total synthesis of the proposed structure of apigenin-5-O-glycoside camellianin B was achieved, wherein three approaches, one linear and two convergent, were established, through which the synthetic structures were firmly corroborated. Meanwhile, through the synthesis of anthentic camellianin B via commercially available camellianin A, the misassigned structures of camellianins A and B were revised. 
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