Synthesis, structure and magnetic behavior of five-coordinate bis(iminopyrrolyl) complexes of cobalt(II) containing PMe3 and THF ligands.

Abstract

The new bis-iminopyrrolyl five-coordinate Co(II) complexes [Co(kappa (2) N, N'-NC 4H 3C(R)N-2,6- (i)Pr 2C 6H 3) 2(PMe 3)] (R = H 3a; Me 3b) were synthesized in high yields (ca. 80-90%), using THF and diethyl ether as solvents, respectively, by (a) treatment of CoCl 2(PMe 3) 2 with the corresponding iminopyrrolyl Na salts ( Ie or If) or (b) reaction of… (More)
DOI: 10.1021/ic800992f

Topics

Cite this paper

@article{Carabineiro2008SynthesisSA, title={Synthesis, structure and magnetic behavior of five-coordinate bis(iminopyrrolyl) complexes of cobalt(II) containing PMe3 and THF ligands.}, author={Sonia A C Carabineiro and Ronan M Bellabarba and Pedro Luciano Teixeira Gomes and Sofia I Pascu and Luis F Veiros and Cristina Freire and Laura C. J. Pereira and Rui Henriques and Maria Conceiç{\~a}o Oliveira and John Warren}, journal={Inorganic chemistry}, year={2008}, volume={47 19}, pages={8896-911} }