Synthesis of two nickel (II) complexes bearing pyrrolide-imine ligand and their catalytic effects on thermal decomposition of ammonium perchlorate

  title={Synthesis of two nickel (II) complexes bearing pyrrolide-imine ligand and their catalytic effects on thermal decomposition of ammonium perchlorate},
  author={Ji-Bin Zhuo and Zai-He Ma and Cai-Xia Lin and Li-Li Xie and Sha Bai and Yaofeng Yuan},
  journal={Journal of Molecular Structure},
Abstract Two pyrrolide-imine chelating Ni(II) complexes {[2-(2-CH 3 O-C 6 H 4 -NCH)C 4 H 3 N] 2 Ni ( 2a ) and [(Fc-NCH)]C 4 H 3 N] 2 Ni ( 2b , Fc = ferrocenyl)} were prepared via treating corresponding Schiff base with 0.5 equiv. NiCl 2 ·6H 2 O in moderate yields. The crystal structures of 2a and 2b were determined by single-crystal X-ray diffraction. Atom Ni(II) of 2a was coordinated by two pyrrolide-imine ligands in trans position to display a twisted octahedral coordination geometry. Ni(II… Expand
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