Synthesis of stachybotrin C and all of its stereoisomers: structure revision.

Abstract

We disclose the first total synthesis of stachybotrin C, a potent neuroprotective natural compound. All of the four stereoisomers have been prepared and fully characterized with the aim to attribute the absolute configuration of the two adjacent stereocenters of the stachybotrin C. 
DOI: 10.1021/jo401116r

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