Synthesis of novel allyl palladium complexes bearing purine based NHC and a water soluble phosphine and their catalytic activity in the Suzuki‐Miyaura coupling in water

@article{Scattolin2018SynthesisON,
  title={Synthesis of novel allyl palladium complexes bearing purine based NHC and a water soluble phosphine and their catalytic activity in the Suzuki‐Miyaura coupling in water},
  author={T. Scattolin and L. Canovese and F. Visentin and Stefano Paganelli and P. Canton and N. Demitri},
  journal={Applied Organometallic Chemistry},
  year={2018},
  volume={32}
}
  • T. Scattolin, L. Canovese, +3 authors N. Demitri
  • Published 2018
  • Chemistry
  • Applied Organometallic Chemistry
    • We have synthesized and fully characterized some novel allyl palladium complexes stabilized by mixed spectator ligands, namely the water soluble sodium 3,3′,3″-phosphinetriyltribenzenesulfonate, (TPPTS) and three carbenes derived from differently alkylated natural xanthines. In order to explore their potential applications we have tested their catalytic activity in the Suzuki-Miyaura coupling of para-bromoacetophenone with phenyl boronic acid, chosen as standard reaction. Only one of the… CONTINUE READING
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