Synthesis of nitrophenyl-substituted 1,3-thiazoline-2-thiones by oxirane ring opening with several dithiocarbamates

@article{Kulakov2010SynthesisON,
  title={Synthesis of nitrophenyl-substituted 1,3-thiazoline-2-thiones by oxirane ring opening with several dithiocarbamates},
  author={Ivan V. Kulakov and A. M. Gazaliev and O. A. Nurkenov and D. M. Turdybekov},
  journal={Chemistry of Heterocyclic Compounds},
  year={2010},
  volume={46},
  pages={490-494}
}
  • Ivan V. Kulakov, A. M. Gazaliev, +1 author D. M. Turdybekov
  • Published 2010
  • Chemistry
  • Thiazolo-2(3H)-thiones have been prepared by the reaction of triethylamine dithiocarbamates and 4-nitrophenyloxirane via formation of intermediate 2-hydroxy-2-(4-nitrophenyl)ethyldithiocarbamates with simultaneous dehydrogenation of the thiazolidine ring to a thiazoline. It was found that both the basicity of the starting amines and the temperature influenced the course of the reaction. 

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