Synthesis of multi-arm-star polyglycidols of different architecture grafted with polyacrylate side arms

@inproceedings{Schmitz2009SynthesisOM,
  title={Synthesis of multi-arm-star polyglycidols of different architecture grafted with polyacrylate side arms},
  author={Christof Schmitz and Helmut Keul and Martin Moeller},
  year={2009}
}
Well defined linear and 3-, 4-, and 6-arm-star shaped polyglycidols were obtained via anionic ring-opening polymerisation of ethoxyethyl glycidyl ether using 3-phenyl-1-propanol, trimethylolpropane, di(trimethylolpropane, and dipentaerythrite as initiator followed by the removal of the acetal protection group via acid catalysed hydrolysis. The microstructure and architecture of the polymers was proven by NMR spectroscopy, size exclusion chromatography and MALDI-TOF-MS. Multifunctional… CONTINUE READING

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