Synthesis of monoclinic potassium niobate nanowires that are stable at room temperature.

@article{Kim2013SynthesisOM,
  title={Synthesis of monoclinic potassium niobate nanowires that are stable at room temperature.},
  author={Seungwook Kim and Ju-Hyuck Lee and Jaeyeon Lee and Sang‐Woo Kim and Myung Hwa Kim and Sungnam Park and Haegeun Chung and Yong-Il Kim and Woong Kim},
  journal={Journal of the American Chemical Society},
  year={2013},
  volume={135 1},
  pages={
          6-9
        }
}
We report the synthesis of KNbO(3) nanowires (NWs) with a monoclinic phase, a phase not observed in bulk KNbO(3) materials. The monoclinic NWs can be synthesized via a hydrothermal method using metallic Nb as a precursor. The NWs are metastable, and thermal treatment at ∼450 °C changed the monoclinic phase into the orthorhombic phase, which is the most stable phase of KNbO(3) at room temperature. Furthermore, we fabricated energy-harvesting nanogenerators by vertically aligning the NWs on SrTiO… 

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References

SHOWING 1-10 OF 23 REFERENCES
Growth of single-crystalline KNbO3 nanostructures.
TLDR
The results indicate that highly uniform single-crystalline nanowires form within a narrow window of the ternary phase diagram of KOH-Nb2O5-H2O.
Enhanced Photocatalytic Water Splitting Properties of KNbO3 Nanowires Synthesized through Hydrothermal Method
Potassium niobate (KNbO3) nanowires were synthesized by a hydrothermal method. X-ray diffraction and Raman spectroscopy indicated the nanowires are well-crystallized with orthorhombic structure. High
Synthesis and characterization of wurtzite-phase copper tin selenide nanocrystals.
TLDR
The wurtzite CTSe nanocrystals possess an optical and electrochemical band gap of 1.7 eV and display an electrochemical photoresponse indicative of a p-type semiconductor.
Growth kinetics of one-dimensional KNbO3 nanostructures by hydrothermal processing routes.
TLDR
A model taking into account the cube-based morphology of the nanostructures, their defects as the KOH proportion in the starting solution increases, and the partial depletion of species in the solution at the kink regions is proposed allows the morphological evolution of the Nanowires and nanofingers to be successfully reproduced, shedding light on the origin of their highly anisotropic growth.
Nonlinear optical response in single alkaline niobate nanowires.
TLDR
By carefully examining nonlinear properties of (XNbO(3)) nanowires the authors suggest which type of wires are best suited for the given application and demonstrate for the first time wave-guiding of SHG signal in all three types of alkaline niobate nanowire.
Crystallographic alignment of high-density gallium nitride nanowire arrays
TLDR
The use of metal–organic chemical vapour deposition (MOCVD) and appropriate substrate selection is demonstrated to control the crystallographic growth directions of high-density arrays of gallium nitride nanowires with distinct geometric and physical properties.
Low-symmetry phases in ferroelectric nanowires.
TLDR
Evidence of a previously unreported ferroelectric ground state of monoclinic symmetry is provided and the tuning of the polarization's direction is tuned by varying factors inherent to the nanoscale.
Chimie Douce Approaches to the Synthesis of Metastable Oxide Materials
While thermodynamically stable metal oxides and other solids could be prepared by conventional high-temperature (ceramic) methods, syntheses of the more important metastable oxide materials of
One‐Dimensional Nanostructures: Synthesis, Characterization, and Applications
This article provides a comprehensive review of current research activities that concentrate on one-dimensional (1D) nanostructures—wires, rods, belts, and tubes—whose lateral dimensions fall
...
1
2
3
...