Synthesis of monoclinic potassium niobate nanowires that are stable at room temperature.
@article{Kim2013SynthesisOM,
title={Synthesis of monoclinic potassium niobate nanowires that are stable at room temperature.},
author={Seungwook Kim and Ju-Hyuck Lee and Jaeyeon Lee and Sang‐Woo Kim and Myung Hwa Kim and Sungnam Park and Haegeun Chung and Yong-Il Kim and Woong Kim},
journal={Journal of the American Chemical Society},
year={2013},
volume={135 1},
pages={
6-9
}
}We report the synthesis of KNbO(3) nanowires (NWs) with a monoclinic phase, a phase not observed in bulk KNbO(3) materials. The monoclinic NWs can be synthesized via a hydrothermal method using metallic Nb as a precursor. The NWs are metastable, and thermal treatment at ∼450 °C changed the monoclinic phase into the orthorhombic phase, which is the most stable phase of KNbO(3) at room temperature. Furthermore, we fabricated energy-harvesting nanogenerators by vertically aligning the NWs on SrTiO…
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References
SHOWING 1-10 OF 23 REFERENCES
Growth of single-crystalline KNbO3 nanostructures.
- Materials ScienceThe journal of physical chemistry. B
- 2006
The results indicate that highly uniform single-crystalline nanowires form within a narrow window of the ternary phase diagram of KOH-Nb2O5-H2O.
Enhanced Photocatalytic Water Splitting Properties of KNbO3 Nanowires Synthesized through Hydrothermal Method
- Chemistry
- 2008
Potassium niobate (KNbO3) nanowires were synthesized by a hydrothermal method. X-ray diffraction and Raman spectroscopy indicated the nanowires are well-crystallized with orthorhombic structure. High…
Synthesis and characterization of wurtzite-phase copper tin selenide nanocrystals.
- Materials Science, ChemistryJournal of the American Chemical Society
- 2012
The wurtzite CTSe nanocrystals possess an optical and electrochemical band gap of 1.7 eV and display an electrochemical photoresponse indicative of a p-type semiconductor.
Hydrothermal synthesis of nonlinear optical potassium niobate ceramic powder
- Materials Science
- 1998
Growth kinetics of one-dimensional KNbO3 nanostructures by hydrothermal processing routes.
- Materials ScienceThe journal of physical chemistry. B
- 2005
A model taking into account the cube-based morphology of the nanostructures, their defects as the KOH proportion in the starting solution increases, and the partial depletion of species in the solution at the kink regions is proposed allows the morphological evolution of the Nanowires and nanofingers to be successfully reproduced, shedding light on the origin of their highly anisotropic growth.
Nonlinear optical response in single alkaline niobate nanowires.
- PhysicsNano letters
- 2011
By carefully examining nonlinear properties of (XNbO(3)) nanowires the authors suggest which type of wires are best suited for the given application and demonstrate for the first time wave-guiding of SHG signal in all three types of alkaline niobate nanowire.
Crystallographic alignment of high-density gallium nitride nanowire arrays
- Materials Science, ChemistryNature materials
- 2004
The use of metal–organic chemical vapour deposition (MOCVD) and appropriate substrate selection is demonstrated to control the crystallographic growth directions of high-density arrays of gallium nitride nanowires with distinct geometric and physical properties.
Low-symmetry phases in ferroelectric nanowires.
- PhysicsNano letters
- 2010
Evidence of a previously unreported ferroelectric ground state of monoclinic symmetry is provided and the tuning of the polarization's direction is tuned by varying factors inherent to the nanoscale.
Chimie Douce Approaches to the Synthesis of Metastable Oxide Materials
- Materials Science, Chemistry
- 1995
While thermodynamically stable metal oxides and other solids could be prepared by conventional high-temperature (ceramic) methods, syntheses of the more important metastable oxide materials of…
One‐Dimensional Nanostructures: Synthesis, Characterization, and Applications
- Materials Science
- 2003
This article provides a comprehensive review of current research activities that concentrate on one-dimensional (1D) nanostructures—wires, rods, belts, and tubes—whose lateral dimensions fall…



