Synthesis of indaphyrins: meso-tetraarylsecochlorin-based porphyrinoids containing direct o-phenyl-to-beta-linkages.

Abstract

The synthesis of indaphyrins, novel meso-tetraarylsecochlorin-derived chromophores incorporating o-phenyl-to-beta-linkages, is described. Oxidative diol cleavage of meso-tetraaryl-2,3-dihydroxy-2,3-chlorins results in the formation of a secochlorin bisaldehyde. Depending on the reaction conditions during the ring cleavage reaction, one or two of the… (More)

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@article{McCarthy2004SynthesisOI, title={Synthesis of indaphyrins: meso-tetraarylsecochlorin-based porphyrinoids containing direct o-phenyl-to-beta-linkages.}, author={Jason R. McCarthy and Michael A Hyland and Christian Br{\"u}ckner}, journal={Organic & biomolecular chemistry}, year={2004}, volume={2 10}, pages={1484-91} }