Synthesis of diversely substituted 2-(furan-3-yl)acetates from allenols through cascade carbonylations.

Abstract

Novel synthesis of diversely substituted 2-(furan-3-yl)acetates via palladium-catalyzed one-pot multi-component reactions of allenols, aryl iodides, alcohols, and carbon monoxide has been developed. Notably, the formation of the title compounds features a cascade process combining carbonylation of aryl iodide, alcohoxyl carbonylation of the in situ formed… (More)
DOI: 10.1039/c5cc06150d

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