Synthesis of axially chiral gold complexes and their applications in asymmetric catalyses

Abstract

Several novel chiral N-heterocyclic carbene and phosphine ligands were prepared from (S)-BINOL. Moreover, their ligated Au complexes were also successfully synthesized and characterized by X-ray crystal diffraction. A weak gold-π interaction between the Au atom and the aromatic ring in these gold complexes was identified. Furthermore, we confirmed the… (More)
DOI: 10.3762/bjoc.9.261

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Cite this paper

@inproceedings{Sun2013SynthesisOA, title={Synthesis of axially chiral gold complexes and their applications in asymmetric catalyses}, author={Yin-wei Sun and Qin Xu and Min Shi}, booktitle={Beilstein journal of organic chemistry}, year={2013} }