Synthesis of arene ruthenium triazolato complexes by cycloaddition of the corresponding arene ruthenium azido complexes with activated alkynes or with fumaronitrile

@article{Singh2006SynthesisOA,
  title={Synthesis of arene ruthenium triazolato complexes by cycloaddition of the corresponding arene ruthenium azido complexes with activated alkynes or with fumaronitrile},
  author={Keisham S. Singh and Kevin A. Kreisel and G. Yap and M. Kollipara},
  journal={Journal of Organometallic Chemistry},
  year={2006},
  volume={691},
  pages={3509-3518}
}
Abstract The neutral arene ruthenium azido complexes [(η6-p-cymene)Ru(LL)(N3)], [LL = acetylacetonato (acac) (4), benzoylacetonato (bzac) (5) diphenylbenzoyl methane (dbzm) (6)] undergo [3+2] cycloaddition reaction with a series of activated alkynes and fumaronitrile to produce the arene ruthenium triazolato complexes: [(η6-p-cymene)Ru(LL){N3C2(CO2R)2}] [LL = (acac), R = Me (7); LL = (bzac), R = Me (8); LL = (dbzm), R = Me (9); LL = (acac), R = Et (10); LL = (bzac), R = Et (11); LL = (dbzm), R… Expand
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