Synthesis of Tetrasilatetrathia[8]circulenes by a Fourfold Intramolecular Dehydrogenative Silylation of C-H Bonds.

Abstract

The first two examples of a tetrasilatetrathia[8]circulene were synthesized in two steps from a tetraiodotetrathienylene by using a fourfold intramolecular dehydrogenative silylation of C-H bonds as the key step. A single-crystal X-ray diffraction analysis revealed that tetrasilatetrathia[8]circulene contains a perfectly planar [8]radialene skeleton. The… (More)
DOI: 10.1002/chem.201700729

Cite this paper

@article{Serizawa2017SynthesisOT, title={Synthesis of Tetrasilatetrathia[8]circulenes by a Fourfold Intramolecular Dehydrogenative Silylation of C-H Bonds.}, author={Yuma Serizawa and Shuhei Akahori and Shohei Kato and Hayato Sakai and Taku Hasobe and Yoshihiro Miyake and Hiroshi Shinokubo}, journal={Chemistry}, year={2017}, volume={23 29}, pages={6948-6952} }