Synthesis and temperature-dependent studies of a perovskite-like manganese formate framework templated with protonated acetamidine.

Abstract

We report the synthesis, crystal structure, thermal, dielectric, phonon and magnetic properties of the [CH3C(NH2)2][Mn(HCOO)3] (AceMn) compound. Our results show that this compound crystallizes in the perovskite-like orthorhombic structure, space group Imma. It undergoes a structural phase transition at 304 K into a monoclinic structure, space group P21/n… (More)
DOI: 10.1039/c7dt01251a

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