Synthesis and structural, spectroscopic, and electrochemical characterization of new ruthenium dimethyl sulfoxide nitrosyls.

@article{Serli2002SynthesisAS,
  title={Synthesis and structural, spectroscopic, and electrochemical characterization of new ruthenium dimethyl sulfoxide nitrosyls.},
  author={Barbara Serli and Ennio Zangrando and Elisabetta Iengo and Giovanni Mestroni and Lesley J Yellowlees and Enzo Alessio},
  journal={Inorganic chemistry},
  year={2002},
  volume={41 15},
  pages={4033-43}
}
The reactivity of ruthenium(II)- and ruthenium(III)-chloride-dimethyl sulfoxide precursors and of the antimetastatic drug [ImH][trans-RuCl(4)(dmso-S)(Im)] (NAMI-A, Im = imidazole, dmso = dimethyl sulfoxide) toward NO was investigated. Treatment of [(dmso)(2)H][trans-RuCl(4)(dmso-S)(2)] and mer-RuCl(3)(dmso)(3) with gaseous NO yielded [(dmso)(2)H][trans-RuCl… CONTINUE READING