[Synthesis and spectral properties of tailed sercine tetraphenylporphyrin cobalt complex].

Abstract

A new tailed sercine tetraphenylporphinatozinc, 5-(p-butoxyphenyl-10,15,20-trichlorophenyl)porphine and cobalt complex (Co[Ser-TPP]) was synthesized and characterized by elementary analysis, UV, IR, 1HNMR and Raman spectra. The electronic absorption spectra of axial coordination reactions of Co[Ser-TPP] with pyridine, 4-methylpyridine, 4-aminopyridine, 4,4-bipyridine, imidazole, 1-methylimidazole and 2-methylimidazole were inverstigated. The results showed that the changes of electronic absorption spectra of Co[Ser-TPP] could be attributed to the axial coordination reactions of Co[Ser-TPP] with pyridine and imidazole series.

Cite this paper

@article{Ni2004SynthesisAS, title={[Synthesis and spectral properties of tailed sercine tetraphenylporphyrin cobalt complex].}, author={Chun-lin Ni and Chun-qiong Zhou and Yu Zhou and Zhi-ke He and Liang-jie Yuan}, journal={Guang pu xue yu guang pu fen xi = Guang pu}, year={2004}, volume={24 4}, pages={437-9} }