Synthesis and metal coordination of thioether containing cyclo‐ and poly(organophosphazenes)

@inproceedings{Diefenbach2000SynthesisAM,
  title={Synthesis and metal coordination of thioether containing cyclo‐ and poly(organophosphazenes)},
  author={Ursula Diefenbach and Angela M. Cannon and Brigitte Stromburg and David L. Olmeijer and Harry R. Allcock},
  year={2000}
}
Several small molecule cyclotriphosphazenes and high polymeric poly(organophosphazenes) with methylthio groups (CH 3 SR) have been synthesized: [NP(OCH 2 CH 2 SCH 3 ) 2 ] n (n = 3, 1; n = 15,000, 5); [NP(OCH 2 CH 2 CH 2 CH 2 SCH 3 ) 2 ] n (n = 3, 2; n = 15,000, 6); [NP(OCH 2 CH 2 CH(SCH 3 )CH 2 CH 2 CH 3 ) 2 ] n (n = 3, 3; n = 15,000, 7); and [NP(OCH 2 C 6 H 4 SCH 3 ) 2 ] n (n = 3, 4; n = 15,000, 8). Both series of compounds possess multiple thioether coordination sites for potential binding to… CONTINUE READING

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