Synthesis and evaluation of a C8 stationary phase on a silica hydride surface by hydrosilation of 1-octyne.

@article{Pesek2003SynthesisAE,
  title={Synthesis and evaluation of a C8 stationary phase on a silica hydride surface by hydrosilation of 1-octyne.},
  author={Joseph J Pesek and Maria T. Matyska and X. Pan},
  journal={Journal of chromatography. A},
  year={2003},
  volume={992 1-2},
  pages={
          57-65
        }
}
The silanization/hydrosilation method is used to bond an alkyne (1-octyne) to a silica hydride surface. The new bonded material is characterized by elemental analysis and diffuse reflectance infrared Fourier transform spectroscopy. The hydrophobic behavior of this material was determined by the retention characteristics of aromatic solutes and the shape selectivity as well as phase classification (monomeric or polymeric) was measured by the polycyclic aromatic hydrocarbon mixture standard… CONTINUE READING