Synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/calichemicin aglycones

@inproceedings{Schoenen1989SynthesisAC,
  title={Synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/calichemicin aglycones},
  author={Frank J. Schoenen and John A Porco and Stuart L. Schreiber and Gregory D. Vanduyne and Jon Clardy},
  year={1989}
}
The synthesis and crystallographic analysis of a bicyclic core related to the esperamicin/calichemicin aglycones is reported. A key reaction involves the skeletal rearrangement of a mesylate derived from a type II Diels-Alder cycloadduct.