Corpus ID: 100873845

Synthesis and crystal structures of a new Cu(I)-complex with 4-amino-3,5-bis(4-pyridyl)-1,2,4-triazole

  title={Synthesis and crystal structures of a new Cu(I)-complex with 4-amino-3,5-bis(4-pyridyl)-1,2,4-triazole},
  author={Jiang Xu-hong},
  • Jiang Xu-hong
  • Published 2011
  • Chemistry
  • Solvothermal reaction of CuBr and 4-amino-3,5-bis(4-pyridyl)-1,2,4-triazole(4-abpt) generate a new complex [CuBr(4-abpt)],the structure of which was determined through infrared spectroscopy,elemental analysis and X-ray single crystal diffraction.Cu(Ⅰ) was four-coordinated with three N atoms and one Br anion,exhibiting tetrahedron geometry.μ3-bridged 4-abpt ligand connected μ3-Cu(Ⅰ) in ab plane and form a two-dimensional(2D) [Cu-(4-abpt)] layer with(4.82) topology.The 3-D supramolecular… CONTINUE READING

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