Synthesis and characterization of heterocyclic disilylchalcogenides.

@article{Xiao2013SynthesisAC,
  title={Synthesis and characterization of heterocyclic disilylchalcogenides.},
  author={Xu-Qiong Xiao and Hui Zhao and Jun Luo and Zheng John Xu and Guo-Qiao Lai and Zhifang Li},
  journal={Dalton transactions},
  year={2013},
  volume={42 11},
  pages={3994-4001}
}
The reaction of a dipotassium silyl dianion (1) with chalcogenide elements (E) does not afford the corresponding silylchalcogenolates, but allows the generation of a series of heterocyclic disilylchalcogenides (E = S (2), Se (3), Te (4)). Under high temperature, compound 4 can be converted into compound 5, a Te analog of compounds 2 and 3. The compounds… CONTINUE READING