Synthesis and characterization of bis(bipyridine)ruthenium(II) complexes with bromo or protected ethynyl β-diketonato ligands

@inproceedings{Munery2008SynthesisAC,
  title={Synthesis and characterization of bis(bipyridine)ruthenium(II) complexes with bromo or protected ethynyl β-diketonato ligands},
  author={Sabrina Munery and Jo{\"e}l Jaud and Jacques Bonvoisin},
  year={2008}
}
A protected ethynyl group was introduced into a γ-position of a (β-diketonato)bis(bipyridine)ruthenium(II) complex through the reaction of the bromo complex and (triisopropylsilyl)-acetylene with very good yield under microwave irradiation. Two new mononuclear mixed-ligand ruthenium(II) complexes with bipyridine (bpy) and functionalized acetylacetonate ion (2,4-pentanedionate, acac − ), [Ru(bpd)(bpy) 2 ](PF 6 ) ( 2 ; bpy = 2,2′-bipyridine, bpd = 3-Bromo-2,4-pentanedionate ion) and [Ru(tipsepd… CONTINUE READING

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