Synthesis and characterization of block comb‐like copolymers P(A‐MPEO)‐block‐PSt

@inproceedings{Li2004SynthesisAC,
  title={Synthesis and characterization of block comb‐like copolymers P(A‐MPEO)‐block‐PSt},
  author={Yu-Gang Li and Peng-Jie Shi and Y. S. Zhou and Cai-Yuan Pan},
  year={2004}
}
Amphiphilic block comb-shaped copolymers, poly[poly(ethylene oxide) methyl ether acrylate]-block-polystyrene [P(A-MPEO)-block-PSt] with PSt as a handle, were successfully synthesized via a macromonomer technique. The reaction of MPEO with acryloyl chloride yielded a macromonomer, A-MPEO. The macroinitiator PSt capped with the dithiobenzoate group (PSt-SC(S)Ph) was prepared by reversible addition–fragmentation transfer (RAFT) polymerization of styrene in the presence of benzyl dithiobenzoate… CONTINUE READING