Synthesis and characterization of di-phenyl-tin(IV)-salicyliden-ortho-aminophenols: analysis of in vitro antitumor/antioxidant activities and molecular structures.

@article{Beltrn2007SynthesisAC,
  title={Synthesis and characterization of di-phenyl-tin(IV)-salicyliden-ortho-aminophenols: analysis of in vitro antitumor/antioxidant activities and molecular structures.},
  author={Hiram I. Beltr{\'a}n and Carlos Dami{\'a}n-Zea and Sim{\'o}n Hern{\'a}ndez-Ortega and Antonio Nieto-Camacho and Mar{\'i}a Teresa Ram{\'i}rez-Ap{\'a}n},
  journal={Journal of inorganic biochemistry},
  year={2007},
  volume={101 7},
  pages={1070-85}
}
The one pot reactions carried among salicylaldehyde 1, ortho-aminophenols 2a-2g, and di-phenyl-tin(IV) oxide 3 led to seven di-phenyl-tin(IV) compounds 4a-4g in good yields (97-83%). All compounds were analyzed by IR, 1H, 13C, 119Sn NMR spectroscopy, mass spectrometry and elemental analyses; furthermore, in the case of compounds 4b, 4c, 4e and 4g by X-ray diffraction. Compounds 4a-4g were tested in vitro against six human tumor cell lines U251, PC-3, K-562, HCT-15, MCF-7 and SKLU-1 to assess… CONTINUE READING
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