Synthesis and characterisation of group nine transition metal complexes containing new mesityl and naphthyl based azaindole scorpionate ligands.


Two novel boron-based flexible scorpionate ligands based on 7-azaindole, Li[HB(azaindolyl)(2)(1-naphthyl)] and Li[HB(azaindolyl)(2)(mesityl)] {Li[(Naphth)Bai] and Li[(Mes)Bai] respectively}, have been prepared (mesityl = 2,4,6-trimethylphenyl). These salts have been isolated in two forms, either as dimeric structures which contain bridging hydride… (More)
DOI: 10.1039/c0dt01576h


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