Synthesis and Structure of Di-[µ-acetato(O,O′)-ferrocenylmethyliden-2,4,6-trimethylaniline(N,C)-palladium(II)]

@article{Blanco1993SynthesisAS,
  title={Synthesis and Structure of Di-[µ-acetato(O,O′)-ferrocenylmethyliden-2,4,6-trimethylaniline(N,C)-palladium(II)]},
  author={Jorge Blanco and E. Garc{\'i}a-Rodeja Gayoso and Jos{\'e} M Vila and M. J. Olay Gayoso and C{\"a}cilia Maichle-M{\"o}ssmer and Joachim Straehle},
  journal={Zeitschrift f{\"u}r Naturforschung B},
  year={1993},
  volume={48},
  pages={906 - 910}
}
Reaction of Na 2 PdCl 4 with N-ferrocenylmethylidene-2,4,6-trimethylaniline yields the dimeric, chloro-bridged Pd(II) complex [Pd{(C 5 H 5 )FeC 5 H 3 C(H)=N-2,4,6-(CH 3 ) 3 C 6 H 2 }Cl] 2 . The title complex (1) is obtained by substitution of the chloro-bridges with acetate. I crystallizes in the orthorhombic space group Pbca with the lattice parameters a=1346.4(4), b=2876.6(2), c=2472.8(5) pm and Z=8. In the dimeric complex each Pd 2+ cation exhibits a square-planar coordination by the N atom… CONTINUE READING

Figures and Tables from this paper.

References

Publications referenced by this paper.
SHOWING 1-6 OF 6 REFERENCES

E

J. L. Casas
  • G ayoso , J. M . Vila, M. T. Pereira, and M . G ayoso , Synth. React. Inorg. M et.-Org. Chem . 21, 263
  • 1991
VIEW 1 EXCERPT

J

A. Suarez
  • M . Vila, M . T. Pereira, E. G ayoso , and M . G ayoso , J. O rganom et. Chem. 335, 359
  • 1987
VIEW 1 EXCERPT

University o f G ö t­ tingen

G . M Sheldrick, S SHELX
  • F R G
  • 1986
VIEW 1 EXCERPT

The Enraf-N onius C A D

B. A . Frenz
  • -S D P . - A Real-Tim e System for C oncurrent X -R ay D ata C ollection and Crystal Structure D eterm ination, Com puting in Crystal­ lography,
  • 1978
VIEW 1 EXCERPT

Purification o f Laboratory

D . D . Perrin, W . L. Arm arego, D. R. Perrin
  • Chem icals,
  • 1966
VIEW 1 EXCERPT