Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes.

Abstract

Sterically hindered, in situ generated 1,3,4-substituted 1,2,3-triazol-5-ylidene mesoionic carbenes (MICs) were employed to stabilize a number of aryl- and heteroaryldihaloboranes, as well as the first MIC-supported diborane. Reduction of borane adducts of the 1-(2,6-diisopropylphenyl)-3-methyl-4-tert-butyl-1,2,3-triazol-5-ylidene ligand with KC8 in non… (More)
DOI: 10.1002/chem.201700500

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