Synthesis and Reactivity of Low-Coordinate Titanium Synthons Supported by a Reduced Redox-Active Ligand.

@article{Clark2016SynthesisAR,
  title={Synthesis and Reactivity of Low-Coordinate Titanium Synthons Supported by a Reduced Redox-Active Ligand.},
  author={Kensha Marie Clark},
  journal={Inorganic chemistry},
  year={2016},
  volume={55 13},
  pages={6443-8}
}
To further explore the reactivity and redox capability of the bis-arylimino acenaphthylene ligand (BIAN) in early transition metal complexes, the coordinatively unsaturated titanium synthons, [(dpp-BAAN)Ti(R)2] ([dpp-BAAN](2-) = N,N'-bis(2,6-diisopropylphenylamido)acenaphthylene and R = O(t)Bu (2) or CH2C(CH3)3 (3)), in which the BAAN ligand is reduced by… CONTINUE READING