Synthesis and Reactivity of Discrete Calcium Imides.

  title={Synthesis and Reactivity of Discrete Calcium Imides.},
  author={Benjamin M. Wolf and Caecilia Maichle-Moessmer and Reiner Anwander},
  journal={Angewandte Chemie},
  volume={55 44},
Protonolysis of dibenzylcalcium with triphenylsilylamine affords a thf-coordinated tetrametallic calcium imide with a heterocuboid core structure. The use of calcium bis(tetramethylaluminate) as a precursor for tandem salt metathesis/protonolysis reactions with alkali metal amides of 2,6-diisopropylaniline and triphenylsilylamine provides access to Lewis… CONTINUE READING