Synthesis and Electrocatalytic Property of Diiron Hydride Complexes Derived from a Thiolate-Bridged Diiron Complex.

Abstract

Interaction of a diiron thiolate-bridged complex, [Cp*Fe(μ-η(2):η(4)-bdt)FeCp*] (1) (Cp* = η(5)-C5Me5; bdt = benzene-1,2-dithiolate) with a proton gives an Fe(III)Fe(III) hydride bridged complex, [Cp*Fe(μ-bdt)(μ-H)FeCp*][BF4] (3[BF4]). According to in situ variable temperature (1)H NMR studies, the formation of 3[BF4] was evidenced to occur through a… (More)
DOI: 10.1021/acs.inorgchem.5b01508

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