Synthesis Structures, and Properties of Functional 2-D Lanthanide Coordination Polymers [Ln2(dpa)2(C2O4)2(H2O)2]n (dpa = 2,2′-(2-methylbenzimidazolium-1,3-diyl)diacetate, C2O42− = oxalate, Ln = Nd, Eu, Gd, Tb)

@article{Wang2010SynthesisSA,
  title={Synthesis Structures, and Properties of Functional 2-D Lanthanide Coordination Polymers [Ln2(dpa)2(C2O4)2(H2O)2]n (dpa = 2,2′-(2-methylbenzimidazolium-1,3-diyl)diacetate, C2O42− = oxalate, Ln = Nd, Eu, Gd, Tb)},
  author={Xiu-Jian Wang and Zhong-Min Cen and Qing-ling Ni and Xuan-Feng Jiang and Heng-Chi Lian and L. Gui and H. Zuo and Zuo-yuan Wang},
  journal={Crystal Growth \& Design},
  year={2010},
  volume={10},
  pages={2960-2968}
}
Four two-dimensional frameworks {[Nd(dpa)(C2O4)(H2O)]·(H2O)}n (1), {[Ln2(dpa)2(C2O4)2(H2O)2]·(H2O)}n (Ln = Eu (2), Gd (3), Tb (4)) (dpa = 2,2′-(2-methylbenzimidazolium-1,3-diyl)diacetate, C2O42− = oxalate) have been synthesized under hydrothermal conditions. The networks were generated via formation of sandwich-like dinuclear secondary building blocks of [Ln2(dpa)2(C2O4)(H2O)2] which are linked to each other, resulting in the formation of the subunit of Ln2O2. The variable-temperature magnetic… Expand
...
1
2
3
4
5
...