Synthesis , characterisation and biological activity of gold ( III ) catecholate and related complexes

@inproceedings{Goss2009SynthesisC,
  title={Synthesis , characterisation and biological activity of gold ( III ) catecholate and related complexes},
  author={Carol H. A. Goss and William Henderson and Alistair L. Wilkins and Cameron and Evans},
  year={2009}
}
The reactions of the cyclometallated gold(III) complexes [LAuCl2] [L = (dimethylaminomethyl)phenyl, 2-benzylpyridyl or 2-anilinopyridyl] with catechol, tetrachlorocatechol, or the cyclic ,-diketone SCH(CO2Et)C(O)C(O)CH(CO2Et) gives stable complexes containing five-membered Au-O-C-C-O rings. These represent the first examples of well-characterised gold(III) catecholate complexes. Similarly, reactions with 2-acetamidophenol [HOC6H4NHC(O)CH3] gives complexes with the related Au-N-C-C-O ring. The… CONTINUE READING

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