Synthesis , Structure , and Spectroscopic Characterization of Unassociated Mono-, Di-, and Triamido Derivatives of Aluminum and Gallium


As part of a study of the possible existence of n-interactions in A1-N or Ga-N bonds, the synthesis and spectroscopic and structural characterization of several unassociated amido derivatives of aluminum and gallium are described. The compounds Mes*GaCl(N(H)Ph}.0.25 (hexane), 1, Mes*zGaN(H)Ph, 2, MesAl(N(SiMe3)2]2, 3, Mes*Ga(NHPh)z, 4, and ClGa{N(SiMe3)2)2… (More)

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