Synthesis , Structure , and Properties of Homoleptic l-Oxa-l , 3-diene Molybdenum and Tungsten Complexes

@inproceedings{Schmidt2013SynthesisS,
  title={Synthesis , Structure , and Properties of Homoleptic l-Oxa-l , 3-diene Molybdenum and Tungsten Complexes},
  author={Thomas Schmidt and Stephan Neis and Richard Goddard},
  year={2013}
}
Z. Naturforsch. 50b, 315-325 (1995); received September 7, 1994 Oxadiene Complex, Molybdenum, Tungsten, X-Ray, Selective Hydrogenation Homoleptic tris(l-oxa-l,3-diene)molybdenum and tungsten complexes are formed as yel­ low, crystalline compounds in 54-80% isolated yield on treatment of the corresponding /3-unsubstituted a,/3-unsaturated ketones with W(CO)3(CH3CH2CN)3 or (y6-C6H6)Mo(CO)3 in refluxing hexane. Reaction of these oxadienes with (^6-C6H 5CH3)2Mo in tetrahydrofuran or /7-hexane… CONTINUE READING