Synthesis, thermal, spectroscopic, and X-ray studies of (dichloroacetato)(triphenylphosphine)gold(I)

  title={Synthesis, thermal, spectroscopic, and X-ray studies of (dichloroacetato)(triphenylphosphine)gold(I)},
  author={J. Skoweranda and Władysław Wieczorek and Maria Bukowska-Strzyżewska and Andrzej Grodzicki and Edward Szłyk},
  journal={Journal of Crystallographic and Spectroscopic Research},
The synthesis, thermal, spectroscopic, and X-ray investigation of (dichloroacetato) (triphenylphosphine)gold(I), [Au(C2HCl2O2)(C6H5)3P] are reported. The thermal analysis showed that the decomposition of the studied complex is a two step process and the mechanism of the decomposition has been proposed. IR and13C NMR spectra of the complex are given. The compound crystallizes in the monoclinic space groupP21/n with four molecules per unit cell.Mr =587.19,a=11.455(1),b=12.398(3),c=14.718(2… CONTINUE READING