Synthesis, structural characterization, thermal and electrochemical studies of the N,N'-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes.

@article{Dolaz2009SynthesisSC,
  title={Synthesis, structural characterization, thermal and electrochemical studies of the N,N'-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine and its Cu(II), Co(II) and Ni(II) metal complexes.},
  author={Mustafa Dolaz and Vickie McKee and Ayşeg{\"u}l G{\"o}lc{\"u} and Mehmet T{\"u}mer},
  journal={Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy},
  year={2009},
  volume={71 5},
  pages={
          1648-54
        }
}
In this study, N,N'-bis[(3,4-dichlorophenyl)methylidene]cyclohexane-1,4-diamine (L) and its Cu(II), Co(II) and Ni(II) complexes were prepared and characterized by the analytical and spectroscopic methods. The analytical data show the composition of the metal complex to be [M(2)L(Cl)(4)(H(2)O)(2)], where L is the Schiff base ligand. The conductance data indicate that all the complexes are non-electrolytes. The compound (L) behaves as a monodentate ligand. But, obtained complexes have binuclear… CONTINUE READING

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