Synthesis, structural characterization, and multichannel anion and cation sensing studies of a bifunctional Ru(II) polypyridyl-imidazole based receptor.

@article{Das2014SynthesisSC,
  title={Synthesis, structural characterization, and multichannel anion and cation sensing studies of a bifunctional Ru(II) polypyridyl-imidazole based receptor.},
  author={Shyamal Das and S. Karmakar and Sourav Mardanya and Sujoy Baitalik},
  journal={Dalton transactions},
  year={2014},
  volume={43 9},
  pages={
          3767-82
        }
}
A mixed-ligand monometallic ruthenium(ii) complex of composition [(bipy)2Ru(tpy-Hbzim-dipy)](ClO4)2 (), where tpy-Hbzim-dipy = 4'-[4-(4,5-di-pyridin-2-yl-1H-imidazol-2-yl)-phenyl]-[2,2';6',2'']terpyridine and bipy = 2,2'-bipyridine has been synthesized and characterized using standard analytical and spectroscopic techniques including X-ray crystallography. The complex displays very intense, ligand centered absorption bands in the UV and moderately intense MLCT bands in the visible region. On… Expand
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