Synthesis, immobilization and catalytic activity of a copper(II) complex with a chiral bis(oxazoline).

@article{Carneiro2014SynthesisIA,
  title={Synthesis, immobilization and catalytic activity of a copper(II) complex with a chiral bis(oxazoline).},
  author={Liliana Carneiro and Ana Raquel Silva and Peter S Shuttleworth and Vitaly L. Budarin and James H. Clark},
  journal={Molecules},
  year={2014},
  volume={19 8},
  pages={11988-98}
}
A chiral bis(oxazoline) bearing CH2OH groups was synthesized from a commercial bis(oxazoline) and characterized by 1H- and 13C-NMR, high resolution ESI-mass spectrometry and FTIR. The corresponding copper(II) complex was immobilized onto the surface of a mesoporous carbonaceous material (Starbon® 700) in which the double bonds had been activated via conventional bromination. The materials were characterized by elemental analysis, ICP-OES, XPS, thermogravimetry and nitrogen adsorption at 77 K… CONTINUE READING