Synthesis, crystal structure and magnetic properties of the spin crossover system [Fe(pq)3]2+

@inproceedings{Jahro2008SynthesisCS,
  title={Synthesis, crystal structure and magnetic properties of the spin crossover system [Fe(pq)3]2+},
  author={Iis Siti Jahro and Djulia Onggo and Ismunandar and Susanto Imam Rahayu and Mar{\'i}a Carmen Aliaga Mu{\~n}oz and Ana Bel{\'e}n Gaspar and Maksym Seredyuk and Philipp Prof. Dr. G{\"u}tlich and Jos{\'e} Antonio Real},
  year={2008}
}
Abstract Three new compounds formulated (ClO 4 ) 2 [Fe(pq) 3 ] ( 1 ), (BF 4 ) 2 [Fe(pq) 3 ] · EtOH ( 2 ) and {(ClO 4 )[MnCr(C 2 O 4 ) 3 ][Fe(pq) 2 (H 2 O) 2 ]} ( 3 ), where pq is 2,2′-pyridylquinoline, have been synthesised and characterised. Despite the different crystal packing exhibited by 1 and 2 , the cationic species [Fe(pq) 3 ] 2+ are structurally quite similar. At 293 K, the Fe–N bond lengths are characteristic of the iron(II) in the high-spin state. In contrast to 1 , 2 undergoes a… CONTINUE READING

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