Synthesis, characterization, and DFT-TDDFT computational study of a ruthenium complex containing a functionalized tetradentate ligand.

Abstract

A ruthenium complex trans-[Ru(L)(NCS)2], L = 4,4' ''-di-tert-butyl-4',4' '-bis(carboxylic acid)-2,2':6',2' ':6' ',2' ''-quaterpyridine (N886), was synthesized and characterized by spectroscopic and electrochemical methods. The absorption spectrum of the N886 complex shows metal-to-ligand charge-transfer transitions in the entire visible region and quasi… (More)

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Cite this paper

@article{Barolo2006SynthesisCA, title={Synthesis, characterization, and DFT-TDDFT computational study of a ruthenium complex containing a functionalized tetradentate ligand.}, author={Claudia Barolo and Md. Khaja Nazeeruddin and Simona Fantacci and Davide Di Censo and Pascal Comte and Paul Liska and Gabriele Viscardi and Pierluigi Quagliotto and Filippo De Angelis and S. Ito and Micha{\"e}l Gr{\"a}tzel}, journal={Inorganic chemistry}, year={2006}, volume={45 12}, pages={4642-53} }