Synthesis, Structures and Reactions of Trimethyltantalum(V) Bis[tri(tert.-butyl)silanolate]

Abstract

Bis[tri(tert.-butyl)silanolato]tantalum(V) trichloride reacts with LiMe to give trimethyl-bis[tri(tert.-butyl)silanolato]tantalum(V), 6. Its molecular structure shows a trigonal-bipyramidal coordination of the Ta atom with the Me groups in the equatorial plane. Its reaction with catecholborane produces preferably B-methyl-catecholborane besides some… (More)

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