Synthesis, Structure, Electrochemical, and Spectroscopic Properties of Hetero-Bimetallic Ru(II)/Fe(II)-Alkynyl Organometallic Complexes.

@article{Sil2019SynthesisSE,
  title={Synthesis, Structure, Electrochemical, and Spectroscopic Properties of Hetero-Bimetallic Ru(II)/Fe(II)-Alkynyl Organometallic Complexes.},
  author={A. Sil and Utsav Ghosh and V. Mishra and Sabyashachi Mishra and S. K. Patra},
  journal={Inorganic chemistry},
  year={2019},
  volume={58 2},
  pages={
          1155-1166
        }
}
A series of heterobimetallic wire-like organometallic complexes [( tpy-C6H4-R)(PPh3)2Ru-C≡C-Fc]+ ( tpy-C6H4-R = 4'-(aryl)-2,2':6',2''-terpyridyl, Fc = [(η5-Cp)2Fe], R = -H, -Me, -F, -NMe2 in complexes 5-8, respectively) featuring ferrocenyl and 4'-(aryl)-2,2':6',2''-terpyridyl ruthenium(II) complexes as redox active metal termini, have been synthesized. Various spectroscopic tools, such as multinuclear NMR, IR spectra, HRMS, CHN analyses, and single crystal X-ray crystallography have been… Expand