Synthesis, Crystal Structure and Thermal Reactivity of [ZnX2(2-chloropyrazine)] (X = Cl, Br, I) Coordination Compounds


Reaction of zinc(II) halides with 2-chloropyrazine in different solvents leads to the formation of five new coordination compounds that contain either only 2-chloropyrazine or additional water molecules as donor ligands. In the ligand-rich 1:2 compound catena[bis(2-chloropyrazine-N)]di-μ-chlorozinc(II) (1) the zinc atom is coordinated by two 2… (More)


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