Synthesis, Characterization, and Molecular Structures of Diethylnitrosamine Metalloporphyrin Complexes of Iron, Ruthenium, and Osmium.

@article{Chen1998SynthesisCA,
  title={Synthesis, Characterization, and Molecular Structures of Diethylnitrosamine Metalloporphyrin Complexes of Iron, Ruthenium, and Osmium.},
  author={Li Chen and Geun-Bae Yi and Li-Sheng Wang and Udeni R. Dharmawardana and Amelia C. Dart and M. Ataullah Khan and George B Richter-Addo},
  journal={Inorganic chemistry},
  year={1998},
  volume={37 18},
  pages={4677-4688}
}
Diethylnitrosamine reacts with [(TPP)Fe(THF)(2)]ClO(4) (TPP = 5,10,15,20-tetraphenylporphyrinato dianion) in toluene to generate the bis-nitrosamine complex, [(TPP)Fe(Et(2)NNO)(2)]ClO(4), in 96% isolated yield. The related [(TTP)Fe(Et(2)NNO)(2)]SbF(6) (TTP = 5,10,15,20-tetra-p-tolylporphyrinato dianion) complex is prepared in 70% isolated yield via a similar reaction in CH(2)Cl(2). Reaction of [(TPP)Fe(Et(2)NNO)(2)]ClO(4) in CH(2)Cl(2) with NO gas results in the displacement of one of the Et(2… CONTINUE READING