Synthesis, π-face-selective aggregation, and π-face chiral recognition of configurationally stable C(3)-symmetric propeller-chiral molecules with a π-core.


The C3 -symmetric propeller-chiral compounds (P,P,P)-1 and (M,M,M)-1 with planar π-cores perpendicular to the C3 -axis were synthesized in optically pure states. (P,P,P)-1 possesses two distinguishable propeller-chiral π-faces with rims of different heights named the (P/L)-face and (P/H)-face. Each face is configurationally stable because of the rigid… (More)
DOI: 10.1002/chem.201400094


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