Syntheses and crystal structures of vanadium and iron chloride complexes with diglyme.

Abstract

A mononuclear molecular complex fac-[VCl3(diglyme)] (1) resulted from the reaction of VCl3 and diglyme (diglyme = di(2-methoxyethyl)ether) in dichloromethane. The violet complex 1 is a sensitive substance which slowly oxidized to a new, blue mononuclear molecular complex, fac-[VOCl2(diglyme)] (2) in the presence of air. The synthesis of iron(II), iron(III… (More)

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