Switchable Site-Selective Catalytic Carboxylation of Allylic Alcohols with CO2.

Abstract

A switchable site-selective catalytic carboxylation of allylic alcohols has been developed in which CO2 is used with dual roles, both facilitating C-OH cleavage and as a C1 source. This protocol is characterized by its mild reaction conditions, absence of stoichiometric amounts of organometallic reagents, broad scope, and exquisite regiodivergency which can… (More)
DOI: 10.1002/anie.201702857

Topics

  • Blog articles referencing this paper

  • Presentations referencing similar topics