Switchable Site-Selective Catalytic Carboxylation of Allylic Alcohols with CO2.


A switchable site-selective catalytic carboxylation of allylic alcohols has been developed in which CO2 is used with dual roles, both facilitating C-OH cleavage and as a C1 source. This protocol is characterized by its mild reaction conditions, absence of stoichiometric amounts of organometallic reagents, broad scope, and exquisite regiodivergency which can… (More)
DOI: 10.1002/anie.201702857


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