Sustained epoxidation of olefins by oxygen donors catalyzed by transition metal-substituted polyoxometalates, oxidatively resistant inorganic analogs of metalloporphyrins.

Abstract

photochemical dissociation of C O from MC1(CO)(PPh3),, they see no net reaction chemistry under the conditions of their experiment.'*2 The formation of benzaldehyde in the present study may result from either a relatively inefficient reaction of MCl(PPh3), with C6H6 leading to arene activation and carbonylation, or from a second photochemical process which… (More)
DOI: 10.1021/ja00263a046

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